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Electric Vehicle Batteries and Boron
11th July 2022 • Borates Today • Brendan McMahon
00:00:00 00:09:57

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In today's podcast, we're going to look at electric vehicle batteries. Electric vehicle batteries are rechargeable batteries that power electric cars bikes and scooters.

They are specifically designed to give power over a sustained period and are deep cycle batteries. Lithium-ion batteries are usually used in EVs. The relatively higher power to weight ratio makes them ideal for powering electric cars and bikes.

Transcripts

Brendan:

Welcome back to the Borates Today podcast.

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Each week we cover a topic that is relevant to the industry and timely.

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We cover the latest industry news.

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Who are the key players in the sector?

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What are the latest trends, driving demand and supply for boron.

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What is the science behind boron and who's doing valuable research into

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new boron applications and benefits?

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We look at how boron helps in advanced energy, in food security,

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and in providing nutrition.

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So don't forget to check out boron applications and benefits

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on our website borates.today.

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In today's podcast, we're going to look at electric vehicle batteries.

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Electric vehicle batteries are rechargeable batteries that power

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electric cars bikes and scooters.

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They are specifically designed to give power over a sustained period

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and are deep cycle batteries.

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Lithium-ion batteries are usually used in EVs.

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The relatively higher power to weight ratio makes them ideal for

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powering electric cars and bikes.

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Electric Vehicle Batteries

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First off, how does an electric vehicle battery function?

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Whereas internal combustion engine cars obtain their energy from

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gasoline or diesel combustion, an electric vehicle draws power

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directly from a large battery pack.

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These packs are similar to a larger version of the lithium-ion

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battery in your phone.

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EVs as they called, don't use a single battery, like a phone but rather a

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pack made up of thousands of individual lithium-ion cells that work together.

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When the car is charging, electricity induces chemical

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changes inside the battery.

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These changes are reversed when the vehicle is on the

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road to generate electricity.

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What about the technology used in electric vehicle batteries?

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These EV batteries go through cycles of discharge while driving and

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charge when the car is plugged in.

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The amount of charge electric vehicle batteries can hold decreases as

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this process is repeated over time.

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This reduces the range and time required between charging journeys.

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The majority of battery manufacturers provide a five to eight year

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warranty on their products.

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Current predictions suggest that electric vehicle batteries will last between 10 and

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20 years before needing to be replaced.

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The connection between a battery and the car's electric

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motor is surprisingly simple.

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The battery connects to one or more electric motors, which drive the wheels.

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When you press the accelerator, the car immediately supplies, power to

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the motor, gradually absorbing the energy stored in the batteries.

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Because electric motors also function as generators, when you take your

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foot off the accelerator, the car begins to slow down by converting its

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forward motion back into electricity.

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This occurs more strongly if you apply the brakes.

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this regenerative braking, recovers energy stored in the battery.

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thus extending the vehicle range.

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Lithium-ion Batteries

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Lithium-ion batteries are lightweight, high capacity batteries commonly used

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in electronic devices, such as laptops, mobile phones, cameras, video game

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consoles, GPS receivers, digital music players and electric cars and bikes.

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These batteries have a high energy density, which means that battery

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manufacturers will be able to save space by decreasing the overall

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size of a battery pack over time.

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Lithium is used.

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It's also the lightest of all metals, which further contributes

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to the compactness of the batteries.

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Another key benefit of lithium ion batteries is that they

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do not contain lithium metal.

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Instead, they rely on ion to create an electric charge.

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This makes it much safer than other batteries that use lithium metal,

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which can be highly volatile.

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How about the use of boron in lithium-ion batteries?

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Lithium-ion batteries rely on graphite as an anode material due to its low

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cost and good properties such as high electrical conductivity and stability.

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However lithium deposition can cause issues that lead to short circuits and

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safety concerns at high charge rates.

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Borate surface coating may safeguard against lithium deposition improving

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the overall stability of the battery which serves as a boundary

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between electrode and electrolyte

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One of the primary challenges of improving lithium-ion batteries is producing a

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highly ordered crystalline graphite structure through high temperature

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heat treatment requiring temperatures in the 3000 degrees centigrade range.

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Still this process can be expensive and energy intensive.

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However, adding borate before graphitization enhances electric

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chemical properties without increasing temperatures as high as with

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standard gravitization processes.

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For increasing crystallinity boron is incorporated into the

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crystalline structure of graphite at higher temperatures that

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activate greater alignment and change the electronic structure.

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Boron acts as an electronic acceptor resulting in a specific

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capacity of 437 milliamps per gram, higher than the standard maximum

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for pure graphite- around 372.

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There is much discussion about recycling electric vehicle batteries.

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Although enabling a second life application can extend battery

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life, electric vehicle batteries must eventually be recycled.

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In many countries, BEV technologies lack a well established recycling

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framework, making BEVs and other battery powered electrical equipment

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a considerable energy expenditure, ultimately increasing CO2 emissions.

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Let's turn to the recycling aspects of EV batteries.

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There are five types of recycling processes currently in use.

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Pyrometallurgical recovery.

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Physical materials separation.

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Hydrometallurgical metal reclamation, a direct to recycling method and

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biological metals reclamation.

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The pyrometallurgical process uses a high temperature furnace to burn the battery

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materials with slag, sand, limestone, and Coke to produce a metal alloy.

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The materials produced are metallic alloys, slag, and gases.

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The gases are evaporated molecules from the electrolytes and by the components.

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In physical materials separation, materials are recovered through

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mechanical crushing and using physical properties such as particle size, density,

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ferro- magnetism and hydrophobicity.

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Sorting can recover copper, aluminum, and steel casing.

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The remaining materials known as black mass, are nickel, cobalt and lithium.

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The hydrometallurgical process separates the metal alloy

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into constituent materials.

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The slag, which is a metal mixture of aluminium, manganese and lithium,

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can be reclaimed and used in the cement industry, for example.

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This method is highly adaptable and relatively risk-free.

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It can work with a wide range of batteries because no pre sorting is required.

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And furthermore, the entire cell is burned.

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So the metal from the current collectors could aid in the smelting process.

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The energy absorption can be reduced by burning electrolyte sand plastics

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due to the exothermic reaction.

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However, this process still necessitates a significant amount of energy.

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And only a limited number of materials can be reclaimed.

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The cathode materials must be crushed to remove the current collection

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for the hydrometallurgical process.

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The cathode materials are then leached by aqueous solutions to extract

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the desired materials from them.

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As the name implies, direct capital recycling extracts the materials directly

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generating a cathode power that can be used as new cathode pristine material.

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This method includes the extraction of electrolytes using

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liquid or supercritical CO2.

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The cathode materials can then be separated after the size of the

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recovered components is reduced.

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And as for the process of biological metals reclamation also known as bio

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leaching, this employs micro organisms that selectively digest metal oxides.

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Recyclers can then reduce the oxides to produce metal nanoparticles.

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Are electric vehicle batteries safe?

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Manufacturers assure us that EV batteries are safe, installing

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smart management systems to prevent overheating and other issues.

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Batteries, however, do get warm during charging and discharging, but vehicles

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are designed to keep them cool.

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High performance EVs may have liquid cooling systems to assist the cooling.

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Despite this, there have been a number of instances of electrical vehicles

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catching fire but very few of these incidents were caused by battery failures.

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They've resulted from accidents that could have caused any car to catch fire such as

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the 2013 case of a Tesla model S colliding with a large piece of metal at high speed.

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In response to the incident, which resulted in a minor fire, tesla CEO,

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Elon Musk stated that electrical vehicle batteries contain only about

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a 10th of the energy of a tank full of fuel, which reduces the danger.

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In fact, according to a 2017 study conducted by the US National Highway

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Traffic Safety Administration, the probability and intensity of fires

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caused by lithium-ion batteries were comparable to, or slightly less than

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that caused by conventional vehicles.

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As more electrical vehicles hit the road, we should be confident that they

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are as safe as traditional vehicles.

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And that's all from Borates Today.

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For more information on electric vehicle batteries, please refer

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to Borates Today, website.

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