Bobby and Allison take Gary to the church of foam and carbonation to explore how beer gets its bubbles. They discuss the molecularly sticky nature of proteins, the dangers of CO2, and the potential effect of other gases on beer.
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CREDITS
Hosts:
Music by Sarah Lynn Huss
Recorded & Produced by David Kalsow
Brought to you by McFleshman's Brewing Co
Welcome to another episode of Respecting the Beer.
2
:My name is Gary Arndt.
3
:And with me again is Bobby
Fleshman and Allison McCoy.
4
:We've talked about.
5
:Sight, how a beer looks, we've
talked about smell, it's aroma.
6
:Today, we're going to talk just
specifically about one aspect
7
:of, of how something looks, and
that is bubbles and carbonation,
8
:a really important part of beer.
9
:We've talked to in an earlier episode, but
the reinheitsgebot and the rules about how
10
:beer could only have three ingredients.
11
:It could have yeast, malt,
and hops now, I guess.
12
:But.
13
:There really is another ingredient
and that ingredient is dissolved
14
:carbon dioxide in most cases, where
does the carbon dioxide come from?
15
:How important is it in the
process of making a beer?
16
:Because we're going to get into
it because not all beers have the
17
:same level of carbonation, right?
18
:Bobby Fleshman: Fermentation
did really cut to the chase.
19
:The core of fermentation is to turn sugar.
20
:into one part alcohol, ethanol,
and one part carbon dioxide.
21
:And you'll get one molecule of
each at the end of the process.
22
:There's a million other steps
along the way, but that is
23
:the core of what's happening.
24
:And in order to do that, you have to
have yeast and you have to have the right
25
:food source, a sugar they can consume.
26
:And that's the job of
the brewer, the maltster.
27
:Gary Arndt: Is the implication of
that, that a higher alcohol beer
28
:is going to have more carbonation.
29
:Bobby Fleshman: If you, so
that's a great question.
30
:It will produce more.
31
:we can't because of the laws of,
of Henry's law, we can't possibly
32
:imagine a way to contain it.
33
:We could maybe from a engineering
standpoint, you would be
34
:talking thousands of pounds of
pressure at the end of the day.
35
:but from a, from a yeast standpoint, they
would obviously not enjoy that too much.
36
:Alison McCoy Fleshman:
I have to interject.
37
:I'm so sorry.
38
:So you can't just say Henry's Law and
assume that everyone knows what that is.
39
:Bobby Fleshman: And that's
why I opened the door here.
40
:Alison McCoy Fleshman: Anyway,
so you've all been there.
41
:You've shaken up a bottle of
soda and then you open up the
42
:soda and guess what happens?
43
:It goes everywhere.
44
:That's Henry's Law.
45
:So the more CO, so CO2 does
not want to be in the water.
46
:the water.
47
:And so it's going to escape,
and it's a gas, so it's going
48
:to escape out of the liquid.
49
:And so Henry's Law tells you
how much of that CO2 you can get
50
:to actually stay in the liquid.
51
:And when you open up that shaken
soda, Henry's Law is like, nope!
52
:Won't stay in.
53
:So out onto you, it comes.
54
:Bobby Fleshman: Right.
55
:So we live and die by Henry's law and
brewing, whether we know it or not.
56
:And it, we can use it when we're using
gas blends and nitrogen and CO2 and so on.
57
:But yeah, you were saying, does
the higher alcohol beer end
58
:up with higher levels of CO2?
59
:No, we tend to, to only leave
in it what we need for balance.
60
:Most beers are.
61
:coming in at, with a, with a range,
but, but they're, they're all in
62
:the sort of the same category.
63
:Alice is waving.
64
:Alison McCoy Fleshman: But so when
you have the big fermenters and we've
65
:normally got the fermenters, this is
the place where we're going to have
66
:the yeast eating the sugar, pooping out
the CO2 and pooping out the alcohol.
67
:So we have a hose that goes down into a
bucket and that bucket is continuously
68
:just bubbling and gurgling, and
really we walk by and we're like,
69
:Oh, the yeast are eating and happy.
70
:But I'm guessing for the higher
alcohol Beer is just more CO2
71
:escapes and we just don't keep it in.
72
:So you're talking about final
product CO2 in the beer.
73
:Whereas I think Gary's talking about
just in the overall process, it should.
74
:So he's right.
75
:It should create more CO2.
76
:Bobby Fleshman: And next step around here.
77
:One of our millions of
projects is to reclaim it.
78
:So once we have it.
79
:We can clean it, make it pure, use it for
what we call tank purging, line purging.
80
:The purpose there is that we want
to make sure that our finished beer
81
:doesn't come into contact with oxygen.
82
:So we create inert environments.
83
:Alison McCoy Fleshman: Speaking of CO2
in the brewing industry CO2, so it was
84
:originally known as fixed air and I
believe, Joseph Priestley back in the
85
:day, gosh, this was like 1800s or so.
86
:or maybe 1700s.
87
:He was an English chemist and he
was playing around with it but
88
:it was called fixed air and they
did all sorts of tricks with it.
89
:And the thing is, is that it sinks
because it's more dense than so CO2 is
90
:more dense than the regular air, which is
oxygen, nitrogen and argon combination.
91
:And so if you happen to be a home brewer
and you are fermenting in a freezer,
92
:like a chest freezer, and I speak from
personal experience, if you drop something
93
:in that chest freezer and go in after it.
94
:Careful because holy hell does it
hurt when you just like embed your
95
:face into just a blanket of co2 you'll
pass out And this is actually how
96
:many people have died in fermenters
when they've gone in to clean them
97
:Bobby Fleshman: Yeah, you don't you don't
actually taste it, but it burns your eyes.
98
:Oh, it hurts.
99
:I think that it burns when
100
:Alison McCoy Fleshman: you can't breathe
it Yeah, so at least in that quantity
101
:Bobby Fleshman: Breathe it
but to no effect, right?
102
:Yeah And there are some non laughable
stories in the last 10 years Modelo
103
:had someone go into a tank to clean
it and the tank was full of CO2.
104
:They didn't have the right equipment.
105
:They passed out.
106
:One person follows them
and next one followed.
107
:Six people died.
108
:They went into this tank
to rescue one another.
109
:So this it's, it's a real dangerous
issue in the brewing industry actually.
110
:But let's, let's get out of that.
111
:We
112
:Alison McCoy Fleshman: have safety things.
113
:Gary Arndt: Yeah.
114
:Back when I was studying geology
in my inorganic chemistry class,
115
:remember we had this really long thing.
116
:Where we had to explain the process by
which CO2 became carbonic acid, right?
117
:in seawater.
118
:Is that process occurring in beer?
119
:Bobby Fleshman: Allison can speak
to that a lot, but you're, you're
120
:making carbonic acid and that's giving
you a bite in the finished product.
121
:And that's, that in addition to the
hop acids are giving you the balance
122
:you're looking for in the end result.
123
:Alison McCoy Fleshman: From my
understanding, it's not very much, it's
124
:not a high concentration of carbonic acid.
125
:Bobby Fleshman: Belgian beers,
however, go double the carbonation
126
:of, of a normal, say, English ale.
127
:So you might see more in that case
because it shifts that, that, chemistry
128
:toward carbonic acid away from CO2.
129
:I did want to say on the high
alcohol that opens the door to
130
:talking a little bit about high,
the effects of alcohol on bubbles.
131
:And they, and alcohol in, in
water tends to change the.
132
:Can you speak to that?
133
:Alison McCoy Fleshman: No, I was like,
have we even talked about bubbles yet?
134
:Bobby Fleshman: Right.
135
:We've, we're kind of coming from
it from the outside in, aren't we?
136
:So bubbles how do you make a
bubble and how do you destroy it?
137
:I think that's probably the best way to.
138
:about bubbles and beer.
139
:My, my men, one of my mentors in
brewing school was Charlie Bamforth
140
:and he's known throughout the
beer world as the Pope of foam.
141
:So he's obsessed with foam and by
proxy, I think I've, I've sort of
142
:become a little bit obsessed too.
143
:He's also a prolific writer of
football, the, the, the worldwide
144
:version of football, but that's
another conversation for another day.
145
:He, would describe bubbles and
make you cry at the end of the day.
146
:I'll do my best here.
147
:Bubbles are protein related.
148
:There's a certain molecular weight
protein that gives you the main amount
149
:of the main structure of these bubbles.
150
:Other elements to the story
include like your double ionized.
151
:metallic ions like calcium, magnesium,
and then you get in hop acids,
152
:Alison McCoy Fleshman: just stop talking
153
:Bobby Fleshman: Starches.
154
:Yeah.
155
:Alison McCoy Fleshman: Wait.
156
:I mean, and I, I'm a chemist.
157
:Bobby Fleshman: I don't have a
picture in front of me, but yeah,
158
:Alison McCoy Fleshman: Let me, let me try.
159
:so imagine you have a balloon
and you blow up that balloon,
160
:you have essentially a bubble.
161
:And so what happens is imagine now that
the proteins and all the molecules Bobby
162
:just mentioned are holding hands in this
nice kind of tight way and then gas.
163
:As in, when you're putting air
into the balloon, expands it out.
164
:So that's what's happening is
the CO2 is encased within these
165
:really well connected structures.
166
:And so they're just
really molecularly sticky.
167
:And so those proteins are love,
well, and this is what gluten
168
:is very sticky molecules.
169
:Anyway, and so the CO2 gets trapped
within these molecules that won't let
170
:it escape because CO2 wants to escape.
171
:This is why if you leave your beer
out for any length of time, it's
172
:going to get flatter and flatter.
173
:Flat means no CO2 anymore.
174
:And so because those CO2 molecules
want to escape, they are trying to,
175
:but they can't because those proteins
are essentially holding them in and
176
:not letting them escape very well.
177
:Bobby Fleshman: There's also that
Henry's law we spoke about too that
178
:there's a natural amount of co2 that
does remain at the end of the day Yeah,
179
:Gary Arndt: it seems you're talking about
there's two different types of bubbles.
180
:There's bubbles in foam, but then
there's the bubbles that come up from the
181
:bottom or the sides of a glass, right?
182
:Bobby Fleshman: So that's so
that's the co2 itself evolving
183
:in order to capture it.
184
:You have to create these these Structures
that I mentioned the compounds involved
185
:and then Allison mentioned how co2 likes
to leave that solution Well, you can
186
:think of the walls of these bubbles as
being Very thin layers of beer and so
187
:they might actually coalesce that is
one bubble becomes to become one They
188
:gas passing from one of the to the other
189
:Alison McCoy Fleshman: But the proteins
aren't those are strong more strongly
190
:Connected to the water and when I
say water I'm talking about beer
191
:So the proteins are more strongly
connected to the beer, which is why
192
:when you have Bubbles, they're not
going to form like soap bubbles that
193
:then rise up and then go float away.
194
:Because those proteins are still strongly
connected molecularly to the beer itself.
195
:Bobby Fleshman: Yeah, proteins
are not evolving away.
196
:CO2 is.
197
:And as the dry, I call it dry, dry foam.
198
:Sometimes people will see me
messing around behind the bar and
199
:it takes me forever to pour beer.
200
:It's not because I'm just trying to get
the perfect shot for a, for a magazine.
201
:It's because I'm letting the,
the beer drain out of the
202
:channels between all the bubbles.
203
:And as the beer drains out, what's
left behind is the, is the protein
204
:and the hop acids and the metal acids.
205
:that are calcium ions, which
is really what they are that
206
:are giving that structure.
207
:And then I'll pour beer
back on top of that.
208
:Again, I'll do it three or four times.
209
:And if you're patient enough, I'll
do it seven times and it'll come
210
:out like the, like a meringue.
211
:And if you've ever made pies and
you've made your meringue that
212
:you're working with proteins there,
you're the albumen of a, of an egg.
213
:So that's what I'm doing back there.
214
:I'm trying to drain the beer off,
make the bubbles have more integrity.
215
:And then the lacing will be profound
after you are finished drinking that.
216
:Alison McCoy Fleshman: We try not to
let him loose in the tap room too often.
217
:Bobby Fleshman: Well, there was one
more thing we should mention and we're
218
:right here on we're hovering on it Co2
and how it likes to escape nitrogen
219
:doesn't like to escape So these little
bubbles when adjacent to one another will
220
:remain adjacent to one another will not
coalesce So you have a very creamy foam
221
:top of your guinness because it's full
of these nitrogen bubbles That have no
222
:means of coalescing and going away that
that's the whole Story behind nitrogen.
223
:Alison McCoy Fleshman: I'm giving
Bobby the look that says you are
224
:absolutely wrong in what you just
said So nitrogen does want to escape
225
:the liquid so it doesn't actually
want to stay because it's nonpolar,
226
:Bobby Fleshman: Right, so but it can't
pass through the the boundaries that
227
:separate the bubble that you are correct.
228
:So they Yeah, yeah, there's
two parts of the story.
229
:So it has to get out of the beer Yeah,
but as soon as it encounters these
230
:films It's at the surface of the beer.
231
:It's a prisoner throughout the pint.
232
:Alison McCoy Fleshman:
And it's much smaller.
233
:The size of the bubble is so much
smaller for nitro based beers or
234
:nitrogenated beers than it is for CO2.
235
:Okay.
236
:Gary Arndt: So let's back up about this.
237
:You serve several nitro beers.
238
:Yes.
239
:How does the nitrogen get in the beer?
240
:Alison McCoy Fleshman:
Oh, we put it there.
241
:Kind of.
242
:Gary Arndt: So I'm just saying in the
natural fermentation process, right,
243
:this is not something that is story.
244
:Alison McCoy Fleshman: Yeast
aren't pooping out nitrogen.
245
:Right.
246
:Gary Arndt: Right.
247
:So.
248
:How do you do it?
249
:Because I know it's not just in beers.
250
:Pepsi's come out with
like a nitrogen version.
251
:Alison McCoy Fleshman: Wait, what?
252
:Are you serious?
253
:Yeah.
254
:Gary Arndt: You didn't see this?
255
:There's like Pepsi nitro.
256
:Alison McCoy Fleshman: Oh weird.
257
:Gary Arndt: Yeah.
258
:So it's, it has a different
feel and everything else.
259
:Where does the nitrogen come from?
260
:Bobby Fleshman: So we can't, we can't
tell this without talking about Guinness.
261
:they can, they decided, so we
make a lot of Cascale here and
262
:that's the old way of doing it.
263
:And you put beer into a keg, if you like,
and you add yeast and sugar and you let it
264
:referment and create its own carbonation.
265
:And that's how it was
done in the old days.
266
:And then you serve it through these
water well type handles that we call beer
267
:engines and people still celebrate today.
268
:Okay.
269
:As being part of the
old way of making beer.
270
:And that makes a creamy little foam
because of the way it's, that you disperse
271
:it through the tips of the system.
272
:And it's, and it looks
a lot like nitrogen.
273
:And in reality, the
story goes the other way.
274
:Nitrogen looks a lot like cask.
275
:Guinness decided it didn't
want to do that much work.
276
:It's a lot of work to do cask.
277
:Alison McCoy Fleshman: So much work that
we are, one of like three or four in the
278
:country that actually specialize in cask
conditioned ales, whereas in England,
279
:everyone does, but here, not so much.
280
:Bobby Fleshman: Less and less in England,
but that's a, Maybe it's changing.
281
:It is a pain in the ass though.
282
:But, I'm not sure where that came
in, but I just wanted to bring it up
283
:that Guinness came up with nitrogen.
284
:That's where it came from.
285
:It's an industrial
addition to the process.
286
:And, Today, how do we
do it in our brewery?
287
:We bought our entire brewing
system for two reasons.
288
:One reason where they came, it
came from the Czech Republic.
289
:Ultimately, maybe we'll talk
about our system in the future
290
:episode, but, one reason was so
I can make German lagers with it.
291
:And the other reason was
so I can make Irish nitro.
292
:The equipment is set up.
293
:To take on more pressure, I can
take advantage of Henry's law
294
:and I can actually put nitrogen
into a state in which it likes
295
:to be dissolved in the beer.
296
:And then from there we can
package it and deliver it through
297
:the standard nitro setups.
298
:But not many people have the equipment
that can go to those pressures.
299
:But I knew that these would
be the linchpins to what we
300
:would be serving down the road.
301
:Gary Arndt: Cask beers, which
you mentioned, if they go
302
:through the same fermentation
process, why are they flatter?
303
:or taste flatter.
304
:Why isn't that they don't have
the same level of carbonation
305
:that you find in say a lager?
306
:Alison McCoy Fleshman:
Because they are superior.
307
:Okay.
308
:Bobby Fleshman: Most days you'll
see me drinking our English IPA.
309
:I like the mouthfeel there.
310
:The reason though that they are that
way is because they are at atmosphere.
311
:And they are at 50 degrees.
312
:So they are whatever
Henry's Law say they are.
313
:Alison McCoy Fleshman: So Henry's Law
will also say that, I mean, and this is
314
:the, the, like I said before, if you leave
your beer or soda, out on the table it's
315
:going to equilibrate to room temperature.
316
:And so it's going to continue
to get warmer and warmer until
317
:it matches room temperature.
318
:And then that's going to cause more
and more of the CO2 to escape the beer.
319
:And so Henry's Law says more of the
gas escapes at the higher temperature.
320
:But I think cask conditioning, that
was how it was for the longest time.
321
:And so I think that the, the colder
beers, we didn't have refrigeration
322
:all the time back in the day.
323
:Bobby Fleshman: Cellars.
324
:Alison McCoy Fleshman: Yeah.
325
:So the cellar temperature
is what they had.
326
:Cause the casks were way down
at the bottom in the basement
327
:cause it kept it cooler.
328
:And so that's one of the reasons that
they had the hand pump technology.
329
:And the folks that used
to do this were called.
330
:publicans and they would work to
tend to the pub or tend to the
331
:firkins or the cask conditioned ales.
332
:But one of the things about
the casks is that it simulates
333
:what beer would have been.
334
:And so back in the day when we
didn't have the technology to have
335
:really high pressure CO2, because
under high pressure is not only
336
:expensive, but it's also dangerous.
337
:And until we had the infrastructure
to build these huge tanks to CO2 and
338
:regulate pressures and stuff, it was
way too dangerous to have anything in a
339
:wooden barrel to be under high pressure.
340
:Actually, you really even couldn't
because you couldn't seal it enough.
341
:Bobby Fleshman: First,
where do you get it?
342
:And then how do you purify it?
343
:How do you transport it?
344
:How do you integrate it?
345
:Yeah.
346
:These are all industrial developments
and, and everything was, was, quote
347
:cascadged at some point in the last
before 150 years ago, for sure.
348
:Everything was.
349
:Yeah.
350
:Yeah.
351
:Gary Arndt: So, in a cast, is
it literally just flat, so far
352
:as the carbonation has escaped?
353
:Bobby Fleshman: So no,
actually this is a process.
354
:So we, we have behind us down the hall,
we have, probably 50 Perkins, which
355
:are large casks ready to be tapped.
356
:And when you tap them initially,
you can't serve them because they
357
:have to do a, go through another
stage of what we call venting.
358
:They have to reach a
Beer is just like people.
359
:Alison McCoy Fleshman: We
all need to vent, don't we?
360
:Bobby Fleshman: So that takes
about a day, if not longer.
361
:Sometimes you get lucky and it's a few
hours, but usually it's going to be a
362
:little angry, little about the change.
363
:Alison McCoy Fleshman: Were the,
let's go back 150 years ago or 200
364
:years ago, were the casks still there?
365
:They were all just wooden
barrels at that point.
366
:Bobby Fleshman: They would
have been pitch lined.
367
:So like sap lined to keep them airtight.
368
:Yeah.
369
:Alison McCoy Fleshman: Didn't know.
370
:Mm hmm.
371
:Because now we use these metal
for can things, the metal casks
372
:and those are gloriously sealed.
373
:Bobby Fleshman: Yeah.
374
:They were, they're glorious.
375
:He's gloriously sealed then too, but you
know, this is a time before microbiology.
376
:So there's a lot of bacteria
and a lot of contamination.
377
:We call it house character.
378
:But yeah.
379
:But to Gary's point though,
that reaches a certain.
380
:Level of carbonation finds equilibrium
with the atmosphere putting in, it's
381
:not an entirely reversible process.
382
:Allison knows more than me, but
putting the CO2 in and then, and then
383
:coming back out, those are different
in terms of time scales and levels.
384
:But you get, you get sort of, an artistic,
input on the whole process as a publican.
385
:I wish that would come back because
we would have more accounts around
386
:the state, people that knows
how to handle these cascades.
387
:Alison McCoy Fleshman: But to
Gary's question, are casks flat?
388
:The answer is that they
are flatter than lagers.
389
:But they shouldn't be completely
flat as in have no CO2 at all.
390
:There is going to be some amount.
391
:It's just going to be
smaller than you're used to.
392
:Bobby Fleshman: The lowest carbonation
beer that we make, beers that we
393
:make are nitro beers, but believe it
or not, they have, they themselves
394
:have carbon dioxide in them.
395
:Alison McCoy Fleshman: Even more
so than our imperial stouts?
396
:Bobby Fleshman: Oh gosh, imperial stouts
have three times as much as our nitro.
397
:Yeah.
398
:It's just that there's so much
sugar in our imperial stout.
399
:Alison McCoy Fleshman: Calculating out
how much carbonation, are you just saying
400
:that nitrogen, because it's nitrogen,
doesn't contribute to carbonation?
401
:Bobby Fleshman: Nitrogen does
not contribute to carbonation.
402
:Alison McCoy Fleshman: Right.
403
:But it's still, so, it's
nitrogenated versus carbonated.
404
:Bobby Fleshman: Yeah, it's about...
405
:Alison McCoy Fleshman: so that's not fair.
406
:It's a different gas.
407
:That's cheating.
408
:Bobby Fleshman: One, one thing
about nitrogen is, you guys wouldn't
409
:believe it, you could hold in your
hand how much nitrogen goes into
410
:600 gallons of, of nitro beer.
411
:Alison McCoy Fleshman: Yeah.
412
:I would totally believe it.
413
:Molecules are small.
414
:Bobby Fleshman: It's astonishing.
415
:Well, but by comparison, you're talking
about thousands of times more for CO2.
416
:Alison McCoy Fleshman: Well, yeah.
417
:It's bigger.
418
:Bobby Fleshman: But the effect of
that tiny amount of nitrogen, it's
419
:parts, it's 40 parts per million.
420
:And Guinness revealed this recipe
on their, somewhere in their
421
:history, in some scientific paper.
422
:And sure enough, if you go
35, you don't get the cascade.
423
:You go 45, half your
glass is full of foam.
424
:It's remarkable.
425
:It's, it's incredibly small amount,
but nitrogen, this whole, this whole
426
:science of beer gas is, is fascinating
427
:Alison McCoy Fleshman: to some,
428
:Bobby Fleshman: to some.
429
:Alison McCoy Fleshman:
No, it really is fun.
430
:And if you have the opportunity to try,
a regular tap beer, a nitro beer and
431
:then a cask beer all at the same time.
432
:It's really fun to just to feel
the different mouth feel that you
433
:get from the different bubbles.
434
:Gary Arndt: Are there any
other gases that you could use?
435
:Is nitrogen pretty much it?
436
:And is it, does the fact that it's
inert, well, relatively inert, a nitrogen
437
:molecule have to do with its use?
438
:Bobby Fleshman: Yes.
439
:but April 1st is coming, so
we should do that helium beer.
440
:I think that should happen because
I want to see, there was a, I
441
:think Sam Adams did this a couple
of years, it's been a decade ago.
442
:They, they joked about doing it and they
were standing around drinking it and then
443
:talking like they had consumed a balloon.
444
:Yeah.
445
:But
446
:Alison McCoy Fleshman: I would say
like the closest relatives to co2 is
447
:like so2 and you would not want sulfur
dioxide in your beer at all nitrogen,
448
:i'm trying to think who the closet
449
:Bobby Fleshman: relative
450
:although sulfur dioxide preserves
the beer It would be disgusting to
451
:Alison McCoy Fleshman: So gross.
452
:No, don't do that.
453
:but no I think conveniently you don't
want oxygen in your beer that's going
454
:to cause a bunch of extra reactions to
occur oxidizing, that sort of thing.
455
:You definitely don't want chlorine
in your beer, cause that'll kill you.
456
:And chlorine's even worse.
457
:Die faster.
458
:So, don't do that.
459
:Gary Arndt: In theory, could you
take a heavier, inert gas, like neon?
460
:Alison McCoy Fleshman:
Ha ha, that'd be fun.
461
:I don't see why not.
462
:Gary Arndt: I mean, it'd
be kind of expensive.
463
:Alison McCoy Fleshman:
Yeah I mean, it would,
464
:Bobby Fleshman: I like
where we're going here.
465
:Alison McCoy Fleshman: No, I don't.
466
:well,
467
:Bobby Fleshman: Five gallons of this.
468
:Alison McCoy Fleshman:
It's to throw Argon in.
469
:Why not?
470
:Krypton, that'd be fun.
471
:Gary Arndt: Argon would be cheaper.
472
:Alison McCoy Fleshman: It would.
473
:I think you, no.
474
:Bobby Fleshman: Food grade Argon.
475
:I'm gonna Google search that.
476
:Alison McCoy Fleshman: I'm about to
look up Henry's constant on Argon.
477
:Cause, yeah, We use argon to like
clean, clean different liquids and
478
:we'll bubble it through to like catch
all the stuff as it bubbles out.
479
:I think the Henry's constant
is just so big you wouldn't
480
:actually have any of the gas stay.
481
:Bobby Fleshman: One other fascinating
thing, I should, I should give
482
:this to this tidbit to the home
brewers and the brewers out there.
483
:You actually do not want to see foam
created in the brewing process or the
484
:fermentation process any more than is
necessary because this is not reversible.
485
:These molecules that made that foam
are lost forever for that application.
486
:So you see, And throughout your packaging
and so on, you want to keep all your
487
:foam down as low as possible beyond just
the loss of beer that's in involved.
488
:So yeah, that's that's chemistry.
489
:It only goes one way in that case.
490
:Gary Arndt: So when you have you
pour a beer, there's foam at the top.
491
:You let it sit for a little while.
492
:That foam will eventually
go down and disappear.
493
:Is all that, I mean, that's obviously
going back into the beer at that point.
494
:Bobby Fleshman: No no.
495
:The proteins themselves
496
:Gary Arndt: I mean it's
got to go somewhere.
497
:Bobby Fleshman: Well, you're probably
consuming them in the first few sips.
498
:You're probably consuming most
of that foam off the surface.
499
:The, the, the, the air that was
holding them bubbles up, CO2 is now
500
:coalescing, gone to the atmosphere.
501
:So it might be a little bit misleading
to, to interpret that much foam as
502
:actually being that much material.
503
:It might be 99 percent CO2.
504
:So when it does completely evolve,
there's not much left to speak of anyway.
505
:But it does, it does give you that lacing
on the sides, which is, Cathedral like,
506
:if you listen to Charlie talk about it.
507
:Yeah.
508
:Hedonic was the word we used.
509
:I'll never forget it.
510
:It's purely hedonic.
511
:Gary Arndt: And Allison,
do you have a calculation?
512
:Alison McCoy Fleshman: I'm trying, I'm
looking, but the units aren't matching
513
:up, so I'm having trouble, because no
one would ever put neon into liquid
514
:because that doesn't help anything.
515
:But Henry's constant is about 0.
516
:03 for CO2, but then it's like 0.
517
:0004.
518
:in neon, but the units are
a little bit different.
519
:It's really, really small.
520
:So cause no neon wants to
stay in any sort of liquid.
521
:So yeah, so brewers out there, sorry,
please do not put neon in your beer.
522
:Gary Arndt: All right.
523
:Well, is there any more
on the subject of bubbles?
524
:Bobby Fleshman: I have
more than we have time for.
525
:I did want to mention
decoction one more time.
526
:A decoction is the way
that we handle grain.
527
:If you go at it from the German
and the check way of doing things,
528
:you, you, you cook it and you
can recombine it in the process.
529
:The point I wanted to bring up here
though, is, is the heating and the
530
:pH that and the time duration that
you apply on that barley and on
531
:that malt gives rise to different
levels of molecular weight proteins.
532
:And ultimately, you can create
amazing foam by doing decoctions.
533
:I'm always going to be a
champion of decoction brewing
534
:for more than one reason.
535
:Alison McCoy Fleshman: I got nothing
to say to that other than everyone
536
:doesn't like you at least in back
of house because of the decoction.
537
:Bobby Fleshman: Until I put
the, the, the results in front.
538
:Alison McCoy Fleshman: Oh,
it tastes so much better.
539
:It really does.
540
:But the process of it, well, it's
kind of like, you know, when you,
541
:you know, you can bake bread.
542
:you know, at home by yourself.
543
:And like, you know, it takes
all this time, or you can
544
:just go buy a nice bread loaf.
545
:But then again, I guess that's what we're
in the business of is making liquid bread.
546
:Bobby Fleshman: The team in the back
of the house are very pragmatic.
547
:They say if it makes the
beer better, they'll do it.
548
:And we put the test in front of them.
549
:And if it, if it's better,
they will jump right in.
550
:Alison McCoy Fleshman: Unless
it's the 36 hour brew day,
551
:which is our Mike Santos, Ph.
552
:D.:
553
:Bobby Fleshman: Including that one, too.
554
:They'll do that too.
555
:Alison McCoy Fleshman: Yay for bubbles.
556
:Gary Arndt: All right, well that concludes
another episode of Respecting the Beer.
557
:Join us next week and until then,
please visit us over on our Patreon page
558
:or over at the Facebook group links of
which can be found in the show notes.